|
|Section2= |Section3= |Section7= |Section8= }} Iron(II) bromide is the chemical compound with the chemical formula FeBr2. This brownish-colored solid is a useful synthetic intermediate; for example it is employed to insert Fe(II) into porphyrins. ==Structure== Like most metal halides, FeBr2 adopts a polymeric structure consisting of isolated metal centers cross-linked with halides. It crystallizes with the CdI2 structure, featuring close-packed layers of bromide ions, between which are located Fe(II) ions in octahedral holes.〔Haberecht, J.; Borrmann, H.; Kniep, R. "Refinement of the Crystal Structure of Iron Dibromide, FeBr2 Zeitschrift für Kristallographie - New Crystal Structures (2001), volume 216, page 510.〕 The packing of the halides is slightly different from that for FeCl2, which adopts the CdCl2 motif. FeBr2 also forms hydrates. 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Iron(II) bromide」の詳細全文を読む スポンサード リンク
|